Category: CLATHRATE (CAVITY INCLUSION, GENERAL)

[NEW] S. Toyota et al., Bull. Chem. Soc. Jpn. 2019, 92, 1721-1728: Nano-Saturn with an Ellipsoidal Body: Anthracene Macrocyclic Ring–C70 Complex.

[NEW] M. A. M. Capozzi, C. Cardellicchio, et al., CrystEngComm 2019, 21, 7224-7232: Stacked aryl groups in P-resolved cyclic phosphonamides as a new conformational constraint, π–π stacking as a conformational constraint in the P-resolved cyclic phosphonamides.

[NEW] M. A. M. Capozzi, C. Cardellicchio, Acta Crystallogr. C, 2019, 75, 189-195: Structural insights into methyl- or methoxy-substituted 1-(α-aminobenzyl)-2-naphthol structures: the role of C—H π interactions.

[NEW] T. Matsuno et al., Nature Comm. 2018, 9, 3779: Concyclic CH-π arrays for single-axis rotations of a bowl in a tube.

[NEW] Y. Yamamoto et al., Angew. Chem. Int. Ed. 2018, 57, 8199-8202. doi: 10.1002/anie.201804430: Nano-Saturn: Experimental Evidence of Complex Formation of an Anthracene Cyclic Ring with C60.

Y. Ruan et al., Chem. Commun. 2014, 50, 9086-9089: On the encapsulation of hydrocarbon components of natural gas within molecular baskets in water. The role of C–H/π interactions and the host's conformational dynamics in the process of encapsulation.

N. Koch et al., Acta Cryst 2014, E70, o393-o394: 2-{2,4,6-Tris(bromo­meth­yl)-3,5-bis­[(1,3-dioxoisoindolin-2-yl)meth­yl]benz­yl}iso­indoline-1,3-dione toluene monosolvate.

L. Mosca et al., Cryst. Growth Des. 2012, 12, 12, 6104–6109: dx.doi.org/10.1021/cg301238e: Host/Guest Complexes of Pentiptycene Receptors Display Edge-to-Face Interaction.

A.-S. Singh, S.-S. Sun, J. Org. Chem., 2012, DOI: 10.1021/jo202502f: Recognition, Encapsulation, and Selective Fluorescent Sensing of Nitrate Anion by C3-Symmetric Tripodal Podands Bearing Amide Functionality.

S. Bracco et al., J. Am. Chem. Soc. 2011, 133, 8982-8994: Supramolecular aggregation of Block Copolymers in the Solid State As Assisted by the Selective Formation of Inclusion Crystals.

Z. Zhang et al., Angew. Chem. Int. Ed. 2011, 50, 1397-1401: Formation of Linear Supramolecular Polymers That Is Driven by CH/pi Interactions in Solution and in the Solid State.

T. Ogoshi et al., Chem. Commun. 2011, 10290-10292: Selective complexation of n-alkanes with pillar[5]arene dimers in organic media.

E. Gagnon et al., Org. Lett. 2010, 12, 380-383: Hexaphenylbenzenes as Potential Acetylene Sponges.

S. Bracco et al., CrystEngComm 2010, 12, 2318-2321: Self-assembly of 1,4-cis-polybutadiene and an aromatic host to fabricate nanostructured crystals by CH-pi interactions.

J.-P. Collin et al., J. Am. Chem. Soc. 2010, 132, 6840-6850: Templated Synthesis of Cyclic [4]Rotaxanes Consisting of Two Stiff Rods Threaded through Two Bis-macrocycles with a Large and Rigid Central Plate as Spacer.

G. Hu et al., J. Am. Chem. Soc. 2009, 131, 15615-15617: Evidence for a Boroxinate Based Br?nsted Acid Derivative of VAPOL as the Active Catalyst in the Catalytic Asymmetric Aziridination Reaction.

S. Tartaggia et al., Org Lett. 2009, 11, 3926-3929: Gases as guests in benzocyclotrimer cage hosts.

J. Kobayashi et al., Chem. Commun. 2009, 6186-6188: Inclusion of C60 into the hexagonal columnar space formed by intra- and intermolecular CH...pi interactions.

Y. Inokuma, A. Osuka, Chem. Eur. J. 2009, 15, 6863-6876: Capped subporphyrins.

V. Chandrasekhar et al., Tetrahedron 2009, 65, 4540-4546: A modular ligand design for cation sensors: phosphorus-supported pyrene-containing ligands as efficient Cu(II) and Mg(II) sensors.

R. Gomes et al., J. Am. Chem. Soc. 2009, 131, 8922-8938: Host-guest interactions between molecular clips and multistate systems based on flavylium salts.

H. J. Choi et al., Chem. Commun. 2009, 131, 4971-4973: New deep cavitand with imidazoquinoxaline flaps: formation of static helical alkane inclusion complexes by enhanced CH/pi interactions.

V. Blanco et al., Org. Lett. 2008, 10, 409-412: Self-Assembly of 1:2 Inclusion Complexes between a Metallocycle Host and Dihydroxyaromatic Guests: A Redox Controlled Complexation Process.

L.-X. Liu et al., Dalton Trans. 2008, 1544-1546: Coordination molecular hats binding acetonitrile via CH/pi interactions.

A. Natarajan et al., J. Am. Chem. Soc. 2007, 129, 4132 -4133: 10.1021/ja070086x: Controlling Photoreactions with Restricted Spaces and Weak Intermolecular Forces: Exquisite Selectivity during Oxidation of Olefins by Singlet Oxygen.

M. Cametti et al., J. Am. Chem. Soc. 2007, 129, 3641 -3648, 10.1021/ja068561z: Ion Pair Recognition of Quaternary Ammonium and Iminium Salts by Uranyl-Salophen Compounds in Solution and in the Solid State.

R. Shukla et al., Chem. Commun. 2007, 3717-3719: Binding of an acetonitrile molecule inside the ethereal cavity of a hexaarylbenzene-based receptor via a synergy of CH-O/CH-pi interactions.

V. Blanco et al., J. Am. Chem. Soc., 2007, 129, 13978-13986: 10.1021/ja074721a: Molecular Catenation via Metal-Directed Self-Assembly and -Donor/-Acceptor Interactions: Efficient One-Pot Synthesis, Characterization, and Crystal Structures of [3]Catenanes Based on Pd or Pt Dinuclear Metallocycles.

K. Kobayashi et al., J. Org. Chem. 2007, 72, 3242 -3246: 10.1021/jo062563k: Orientational Isomerism Controlled by the Difference in Electronic Environments of a Self-Assembling Heterodimeric Capsule.

Y. Habata et al., Inorg. Chem 2007, 46, 6529-6534, 10.1021/ic700538f : Substituent Effects on the Structures of Silver Complexes with Monoazatrithia-12-Crown-4 Ethers Bearing Substituted Aromatic Rings.

A. Comotti et al., J. Am. Chem. Soc. 2007, 129, 8566-8576: 10.1021/ja071348y: 2D Multinuclear NMR, Hyperpolarized Xenon and Gas Storage in Organosilica Nanochannels with Crystalline Order in the Walls.

Y. Tachibana et al., J. Org. Chem. 2006, 71, 5093-5104. 10.1021/jo0601563: Sequential O- and N-Acylation Protocol for High-Yield Preparation and Modification of Rotaxanes: Synthesis, Functionalization, Structure, and Intercomponent Interaction of Rotaxanes.

H. Bakirci et al., J. Org. Chem. 2005, 70, 9960-9966. 10.1021/jo051689z: Spherical Shape Complementarity as an Overriding Motif in the Molecular Recognition of Noncharged Organic Guests by p-Sulfonatocalix[4]arene: Complexation of Bicyclic Azoalkanes.

H. Iwamoto et al., Tetrahedron Lett. 2005, 46, 6839-6842: Conformational control of flexible molecular tweezers by intramolecular CH/pi interaction.

Y. Liu et al., Chem. Commun. 2005, 2211-2213: A unique tetramer of 4: 5 beta-cyclodextrin/ferrocene in the solid state.

B.-L. Poh, C. M. Teem, Tetrahedron 2005, 61, 5123-5129: A 1H NMR study on the complexation of tetraalkylammonium cations, mono and diprotonated amines, and amino acids with a derivatized cyclotetrachromotropylene in an aqueous solution.

A. Ragusa et al., Chem. Eur. J. 2005, 11, Novel enantioselective receptors for N-protected glutamate and aspartate.

Y. Liu et al., J. Am. Chem. Soc. 2004, 126, 9150 -9151. 10.1021/ja048164t: Thermally and Electrochemically Controllable Self-Complexing Molecular Switches.

P. Sozzani et al., Angew. Chem. Int. Ed. 2004, 43, 2792-2797: A familly of supramolecular frameworks of polyconjugated molecules hosted in aromatic nanochannels.

P. Sozzani et al., Chem. Commun. 2004, 768-769: Cooperation of multiple CH-pi interactions to stabilize polymers in aromatic nanochannels as indicated by 2D solid state NMR.

F.-G. Klaerner, B. Kahlert, Acc. Chem. Res. 2003, 36, 919-932: Molecular tweezers and clips as synthetic receptors; Molecular recognition and dynamics in receptor-substrate complexes. [REVIEW]

A. Scarso et al., Angew. Chem. Int. Ed. 2003, 42, 5499-5502: Encapsulation Induces Helical Folding of Alkanes.

E. Meyer et al., Angew. Chem., Int. Ed. Engl. 2003, 42, 1210-1250: Interactions with aromatic rings in chemical and biological recognition.

T. Nabeshima et al., J. Am. Chem. Soc. 2003, 125, 28-29: Remarkably large positive and negative allosteric effects on ion recognition by the formation of a novel helical pseudocryptand.

T. Kawase et al., Angew. Chem. Int. Ed. 2003, 42, 1621-1624: All-hydrocarbon inclusion complexes of carbon nanorings.

A. Frontera et al., Org. Lett., 2003, March 12, on the web (http://dx.doi.org/10.1021/ol034247n): Weak C-H/pi interaction participates in the diastereoselectivity of a host-guest complex in the presence of six strong hydrogen bonds.

S. Apel et al., Chem. Eur. J. 2002, 8, 3678-3686: Weak hydrogen bonding as a basis for concentration-dependent guest selectivity by a cyclophane host.

H. Kurebayashi et al., Tetrahedron 2001, 57, 8667-8674: Structure of supramolecular complex of flexible molecular tweezers and planar guest in solution.

E. L. Piatnitski et al., Chem. Eur. J. 2000, 6, 999-1006: Highly organized spherical hosts that bind organic guests in aqueous solution with micromolar affinity: microcalorimetry studies.

H. Takahashi et al., Tetrahedron 2000, 56, 6185-6191: CH-pi interactions as evidenced in the crystal structure of host-guest complexes. A database study. [See page 'Our papers' for Abstract]

K. Kobayashi et al., Tetrahedron Lett. 1999, 8883-8886: Self-assembly of cavitand tetracarboxylic acid: highly porous packing structure of one-dimensional hydrogen-bonded network.

H. Houjou et al., Tetrahedron Lett. 1999, 40, 6639-6642: Synthesis and crystal structures of novel macrocyclic compounds and their inclusion phenomenon.

A. Furer et al., Helv. Chim. Acta 1999, 82, 1843-1859: Structure-function relationships in the complexation of steroids by a synthetic receptor.

W. Boomgaarden et al., Chem. Eur. J. 1999, 5, 345-355: Broad molecular ribbons of nanometer size composed of biphenyl units.

M. Kamieth et al., Angew. Chem. Int. Ed. Engl. 1998, 37, 3303-3306: Modeling the supramolecular properties of aliphatic-aromatic hydrocarbons with convex-concave topology.

R. G. Chapman et al., J. Am. Chem. Soc. 1998, 120, 6252-6260: Crystal structure and thermodynamics of reversible molecular capsules.

B. M. O'Leary et al., J. Am. Chem. Soc. 1997, 119, 11701-11702: Ring inversion dynamics of encapsulated cyclohexane.

V. Hensel et al., Angew. Chem. Int. Ed. Engl. 1997, 36, 2654-2656: Repetitive construction of macrocyclic oligophenylenes.

P. Wallimann et al., Chem. Rev. 1997, 97, 1567-1608 : Steroids in molecular recognition [REVIEW].

M. Kodama, Bull. Chem. Soc. Jpn. 1996, 69, 3179-3186: Macrocyclic polyazacycloallrane-poly-N-carboxylate anion as a receptor for amino acid.

F. Vogtle et al., Liebigs Ann. 1996, 1697-1704: Concave macrocycles: Absorption spectra, luminescence properties, and endocavital complexation of neutral organic guests.

S. Breidenbach et al., J. Chem. Soc., Perkin Trans. 1 1996, 2061-2067: From four-fold functionalised [3.3]cyclophanes to belt-shaped and multibridged molecules.

F.-G. Klaerner et al., Angew. Chem., Int. Ed. Engl. 1996, 35, 1130-1132: Molecular tweezers as synthetic receptors in host-guest chemistry: Inclusion of cyclohexane and self-assembly of aliphatic side chains.

B. Hinzen et al., Helv. Chim. Acta 1996, 79, 942-960: Mimicking the vancomycin carboxylate binding site: Synthetic receptors for sulfonates, carbohydrates, and N-protected alpha-amino acids in water.

T. Steiner, W. Saenger, J. Chem. Soc., Chem. Commun. 1995, 2087-2088: Weak polar host-guest interactions stabilizing a molecular cluster in a cyclodextrin cavity: CH/O and CH/pi contacts in beta-cyclodextrin-but-2-yne-1,4-diol heptahydrate.

W. Josten et al., Chem. Ber. 1994, 127, 2089-2096: Ein neues deltaphan und bandformige cyclophane.

J. E. Cochran et al., J. Am. Chem. Soc. 1992, 114, 2269-2270: Pi-hydrogen bonds as a design principal in molecular recognition.

C. A. Hunter, J. Chem. Soc., Chem. Commun. 1991, 749-750: Molecular recognition of p-benzoquinone by a macrocyclic host.

F. Diederich, Angew. Chem. Int. Ed. Engl. 1988, 27, 362-386: Complexation of neutral molecules by cyclophane hosts.

K. Odashima et al., J. Am. Chem. Soc. 1980, 102, 2504-2505: Host-guest complex formation between a water soluble polyparacyclophane and a hydrophobic guest molecule.

G. D. Andreeti, R. Ungaro, A. Pochini, J. Chem. Soc., Chem. Commun., 1979, 1005-1007. Crystal and molecular structure of cyclo{quater[(5-t-butyl-2-hydroxy-1,3-phenylene)methylene]} toluene (1 : 1) clathrate with toluene